In the quantum mechanics, every particle is also a wave . As we know from daily life, light waves (photon particles) scatter as they pass through raindrops and formed a rainbow. We assume that an electron does not undergo such scattering due to its movement in the crystal lattice medium.
Our other most remarkable assumption is the tight-binding approach. According to this approach, electrons can only tunnelling into the nearest neighboring atomic orbitals. Thus, we make our work easier by ignoring interactions with distant neighbors.
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